带电导体椭球表面的电荷密度与电场

利用极限情形推断了带电导体椭球表面的电荷密度与电场强度.     

类钾离子4s 2S1/2─3d 2D3/2电四极矩E2光谱跃迁的理论研究

采用全相对论量子力学GRASP²程序,广义平均能级EAL模型,在核的有限体积效应,Breit和QED效应的高阶扰动基础上,考虑到原子实的极化,系统地计算了高剥离类钾离子4s ²S_1/2─3d ²D_3/2电四极矩E2光谱跃迁的能级间隔,跃迁概率和振子强度,结果表明：考虑原子实极化效应后,计算的精细能级结构间隔与实验数据之间的系统误差基本消除,其跃迁概率和振子强度属首次报道. 关键词： 高剥离态 能级间隔 振子强度     

硼掺入量对含硼金刚石单晶热稳定性的影响

 在铁基触媒原材料中添加不同含量的六方氮化硼,采用粉末冶金方法制备片状触媒,在六面顶压机上合成出含硼金刚石单晶。用体视显微镜对金刚石单晶的结构、形貌进行观察,并用电子探针（EPMA）和波谱仪（WDS）分析了金刚石（111）晶面的硼含量,发现金刚石表面有硼元素存在,且其含量随着触媒中掺硼量的增加而变化。在测定了含硼金刚石单晶的静压强度的基础上,采用冲击韧性测定仪和差热分析仪对不同掺硼量触媒合成出的金刚石单晶在空气中的热稳定性进行了系统的对比研究。结果表明,触媒掺硼量对金刚石的机械强度和热稳定性有重要影响,随着掺硼量的变化,其机械强度和热稳定性均存在一个最佳值。     

冲击熔化区材料强度的重整化解析

 采用重整化理论对材料在冲击熔化去的强度进行了分析,分析结果表明在冲击熔化区内,材料的强度在熔化质量分数达到0.300 798时开始减小,与材料中纵波声速向体波声速的转变点相对应。     

高疲劳寿命氯丁橡胶基减振材料的结构与性能

以氯丁橡胶(CR)为基体材料, 将新型反式-1,4-丁二烯-异戊二烯共聚橡胶(TBIR)引入传统CR减振基体中, 探讨TBIR在减振材料中的应用前景. 研究发现, 随着TBIR用量的增加, CR/TBIR混炼胶的强度及模量明显提升; CR/TBIR硫化胶的拉伸强度、 撕裂强度、 压缩永久变形、 动静刚度比及耐疲劳性能均得到改善, 特别是一级疲劳寿命提高了50%~400%(未填充体系)及40%~180%(填充体系), 六级疲劳寿命提高了60%~500%(未填充体系)及30%~120%(填充体系). 与未填充CR/TBIR硫化胶相比, 填充CR/TBIR硫化胶由于炭黑补强作用及填料-聚合物相互作用的引入, 屈挠疲劳寿命、 撕裂强度及拉伸性能均显著提高. 与填充CR硫化胶相比, 填充CR/TBIR质量比为90/10的并用胶能够在保持硫化胶的损耗因子基本不变的基础上, 实现综合性能的平衡提升.     

Viscoelastic modeling of extrusion damage in elastomer seals

ABSTRACT

The viscoelastic behavior of elastomers manifests itself in numerous ways depending on the application. In seals, the viscoelastic response of an elastomer is complex as it depends upon the specific combination of loading pressures, loading rates, chemical environment, temperature and time of loading, and ultimately long-term effects such as creep or stress relaxation can result in seal failure. One specific mechanism encountered in seals under large pressures is extrusion damage. When a seal is pressurized by a fluid, the elastomer is highly constrained; however, there is typically a very small gap between the inner and outer sealing surfaces. Over time viscoelastic creep causes the elastomer to gradually extrude into this gap until the seal ruptures. In this paper the viscoelastic creep behavior of a typical sealing elastomer, NBR, was studied. Compression creep tests were carried out over a range of strains and the measured data were used to develop a strain-dependent viscoelastic material model. The model was then implemented into a finite element analysis (FEA) simulation to study the extrusion creep behavior of an O-Ring seal. Data from the FEA model were then compared against physical test data from equivalent extrusion tests. The FEA model correlated well to the physical test data, with the strain-dependent viscoelastic material model allowing compression creep data to be used to accurately predict extrusion creep.     

Structural characterization of a hybrid terpyridine–pyrazine ligand and its one‐dimensional ZnII coordination polymer: a computational approach to conventional and nonconventional intermolecular interactions

The structures of a new hybrid terpyridine–pyrazine ligand, namely 4′‐[4‐(pyrazin‐2‐yl)phenyl]‐4,2′:6′,4′′‐terpyridine (L2), C₂₅H₁₇N₅, and its one‐dimensional coordination polymer catena‐poly[[bis(acetylacetonato‐κ²O,O′)zinc]‐μ‐4′‐[4‐(pyrazin‐2‐yl‐κN⁴)phenyl]‐4,2′:6′,4′′‐terpyridine‐κN¹], [Zn(C₅H₇O₂)₂(C₂₅H₁₇N₅)]_n or [Zn(acac)₂(L2)]_n (Hacac is acetylacetone), are reported. Packing interactions in both crystal structures are analyzed using Hirshfeld surface and enrichment ratio techniques. For the simpler structure of the monomeric ligand, further studies on the interaction hierarchy using the energy framework approach were made. The result was a complete picture of the intermolecular interaction landscape, which revealed some subtle details, for example, that some weak (at first sight negligible) C—H…N interactions in the structure of free L2 play a relevant role in the crystal stabilization.     

黑体辐射中两类粒子的辐射规律

考虑到相对论效应,采用量子统计的方法,得到了满足Bose-Einstein统计分布和Fermi-Dirac统计分布的两类粒子的黑体辐射公式（包括Planck黑体辐射公式）．发现辐射谱不仅与黑体的辐射温度有关,还与辐射粒子的能量、化学势和种类有关．辐射强度与辐射粒子的能量、静质量、简并因子有关。     

On Nearest Neighbor Classification Using Adaptive Choice of k

Nearest neighbor classification is one of the simplest and popular methods for statistical pattern recognition. It classifies an observation x to the class, which is the most frequent in the neighborhood of x. The size of this neighborhood is usually determined by a predefined parameter k. Normally, one uses cross-validation techniques to estimate the optimum value of this parameter, and that estimated value is used for classifying all observations. However, in classification problems, in addition to depending on the training sample, a good choice of k depends on the specific observation to be classified. Therefore, instead of using a fixed value of k over the entire measurement space, a spatially adaptive choice of k may be more useful in practice. This article presents one such adaptive nearest neighbor classification technique, where the value of k is selected depending on the distribution of competing classes in the vicinity of the observation to be classified. The utility of the proposed method has been illustrated using some simulated examples and well-known benchmark datasets. Asymptotic optimality of its misclassification rate has been derived under appropriate regularity conditions.     

对估算金属切口强度的能量法与Neuber法的比较

估算金属切口的强度时,人们一般采用以Neuber准则为理论基础的Neuber法,或以Moski及Glinka的等效能量密度法为理论基础的能量法．本文以弹塑性幂硬化材料为研究对象,将两种方法得到的结果与实验结果进行了比较,发现Neuber法总是低估切口强度,而大多数情况下,能量法却高估切口强度,并且总的来说,能量法的精度高于Neuber法的精度;能量法的可靠性高于Neuber法的可靠性．